Noninnocent Ligands as a Design Strategy for Fully Compensated Ferrimagnetism in Two-Dimensional Metal–Organic Frameworks
retains fully compensated ferrimagnetism and exhibits a near-Fermi quasi-Dirac-like band feature with an estimated magnetic transition temperature of 132 K. Extended studies of nitrogen- and phosphorus-based ligands further support the generality and boundary of this approach. These findings establish NIL-directed charge transfer as a chemically programmable handle for engineering 2D-compensated magnets.
Authors
- Xiaojun Wu (ORCID: https://orcid.org/0000-0003-3606-1211)
- Yixuan Che (ORCID: https://orcid.org/0000-0002-3990-6868)
- Haifeng Lv (ORCID: https://orcid.org/0000-0001-9491-6367)
- Jinlong Yang (ORCID: https://orcid.org/0000-0002-5651-5340)
- Yuxuan Li
Institutions
- University of Science and Technology of China (CN)
- Hefei University (CN)
- Hefei National Center for Physical Sciences at Nanoscale (CN)
- Microscale (United States) (US)
- Collaborative Innovation Center of Chemistry for Energy Materials (CN)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-07-26
- DOI
- https://doi.org/10.1021/jacs.6c06650
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00