Structure and Compressional Behavior of Sillén-Type (BiO) <sub>2</sub> (CO <sub>3</sub> ) Bismutite Carbonate
direction perpendicular to those layers, which we justify on the basis of the bismuth lone electron pair compressibility and the slight reorientation of the carbonate groups. Raman spectroscopy measurements at ambient conditions and under pressure were used to characterize the vibrational properties of this carbonate, unvealing a differentiated behavior of the nonequivalent carbonate units.
Authors
- Julio Pellicer‐Porres (ORCID: https://orcid.org/0000-0002-4288-900X)
- Alberto Otero‐de‐la‐Roza (ORCID: https://orcid.org/0000-0002-6334-3516)
- Raquel Chuliá-Jordán
- Ganesh Bera (ORCID: https://orcid.org/0000-0002-6766-6902)
- B Wang
- David Santamarı́a-Pérez (ORCID: https://orcid.org/0000-0002-1119-5056)
- Lkhamsuren Bayarjargal (ORCID: https://orcid.org/0000-0002-5513-591X)
- Benedito Donizeti Botan-Neto (ORCID: https://orcid.org/0000-0002-1498-988X)
- Julia Bungarten
- Catalin Popescu
Institutions
- Goethe University Frankfurt (DE)
- Universitat de València (ES)
- Universidad de Oviedo (ES)
- ALBA Synchrotron (Spain) (ES)
- Deutsches Elektronen-Synchrotron DESY (DE)
- Centro de Ciencias Humanas y Sociales (ES)
- Rede de Química e Tecnologia (PT)
- Fundación General (ES)
- Instituto de Química y Fisicoquímica Biológicas (AR)
- Institute of Geosciences
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-07-26
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c01891
- Primary Topic
- High-pressure geophysics and materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00