Dynamic Coordination-Enabled Metal-Dependent Configurational Switching in a Covalent Organic Framework
regeneration, whereas COF-LIFM20-Cu significantly suppresses the activity, enabling metal-induced configurational regulation of photocatalytic performance. This work establishes a versatile strategy for constructing reconfigurable COFs through the integration of dynamic covalent and coordination chemistry, providing new opportunities for developing adaptive crystalline materials with programmable structures and tunable functionalities.
Authors
- Cheng‐Yong Su (ORCID: https://orcid.org/0000-0003-3604-7858)
- Zhiye Zhong
- J Y Chen
- H Chen
- Hai‐Sen Xu (ORCID: https://orcid.org/0000-0003-4137-9005)
- Dieter Fenske (ORCID: https://orcid.org/0000-0002-2812-7279)
- Xiao‐Chun Lin
- Jia Liu (ORCID: https://orcid.org/0000-0002-5470-7525)
- Hongfei Wang (ORCID: https://orcid.org/0000-0002-7828-9428)
- Wei-De Zhu
- Wen-Na Jiao
- Si Huang
- Liang Song
Institutions
- Karlsruhe Institute of Technology (DE)
- National University of Singapore (SG)
- Institute of Molecular Functional Materials (CN)
- Université Bourgogne Franche-Comté (FR)
- Institute of Nanotechnology (GB)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-07-27
- DOI
- https://doi.org/10.1021/jacs.6c10544
- Primary Topic
- Covalent Organic Framework Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- National Key Research and Development Program of China