Unveiling Anion-Dependent Redox Kinetics of the V <sup>4+</sup> /V <sup>5+</sup> Couple in Acidic Electrolytes: A Combined Powder Microelectrode and Intervalence Charge Transfer Study

electron transfer kinetics, which is further corroborated by Raman spectroscopy. This work provides a reliable approach to evaluate ET kinetics and offers theoretical guidance for designing high-performance VRFBs.

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Publication Details

Journal
The Journal of Physical Chemistry Letters
Published
2026-07-26
DOI
https://doi.org/10.1021/acs.jpclett.6c01572
Primary Topic
Advanced battery technologies research
Type
article
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article

Unveiling Anion-Dependent Redox Kinetics of the V 4+ /V 5+ Couple in Acidic Electrolytes: A Combined Powder Microelectrode and Intervalence Charge Transfer Study

Hanbing Liu, Zhangquan Peng, Chao Wang, M T Wu
The Journal of Physical Chemistry Letters
Advanced battery technologies research
article

Unveiling Anion-Dependent Redox Kinetics of the V 4+ /V 5+ Couple in Acidic Electrolytes: A Combined Powder Microelectrode and Intervalence Charge Transfer Study

Hanbing Liu, Zhangquan Peng, Chao Wang, M T Wu
article en

Abstract

electron transfer kinetics, which is further corroborated by Raman spectroscopy. This work provides a reliable approach to evaluate ET kinetics and offers theoretical guidance for designing high-performance VRFBs.

The Journal of Physical Chemistry Letters
University of Science and Technology of China (CN), Chinese Academy of Sciences (CN), Electrotechnical Institute (PL), University of Chinese Academy of Sciences (CN)
Affordable and clean energy
Openalex Percentile: Top 15%
Advanced battery technologies research
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Unveiling Anion-Dependent Redox Kinetics of the V <sup>4+</sup> /V <sup>5+</sup> Couple in Acidic Electrolytes: A Combined Powder Microelectrode and Intervalence Charge Transfer Study — Hanbing Liu, Zhangquan Peng, et al. · The Journal of Physical Chemistry Letters (2026) | TGRS Research Map | TGRS