Interpenetration Control in Three-Dimensional Covalent Organic Frameworks: Architectural Modulation and <i>cis</i> -Imine Configuration
isomerization, imparting pronounced framework flexibility and driving an exceptional ∼220% expansion of the crystal volume. This work provides the systematic experimental demonstration that interpenetration can be harnessed to govern both framework architecture and dynamic behavior, highlighting its key role in designing 3D COFs with tailored functions.
Authors
- Ziqiu Ye
- Bo Gui (ORCID: https://orcid.org/0000-0002-4569-526X)
- Cheng Wang (ORCID: https://orcid.org/0000-0003-0326-2674)
- Junliang Sun (ORCID: https://orcid.org/0000-0003-4074-0962)
- 谭文恕
- Honglin Du (ORCID: https://orcid.org/0000-0002-1165-6545)
Institutions
- Peking University (CN)
- Wuhan University (CN)
- Beijing National Laboratory for Molecular Sciences (CN)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-07-26
- DOI
- https://doi.org/10.1021/jacs.6c08384
- Primary Topic
- Covalent Organic Framework Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00