Monolayer <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>MnBi</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi>Te</mml:mi> <mml:mn>4</mml:mn> </mml:msub> </mml:mrow> </mml:math> : Atomic-scale insigh

As the first intrinsic antiferromagnetic topological insulator, ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ offers a platform for investigating topological phenomena driven by magnetism. Prior studies focused on bulk single crystals and exfoliated flakes, but the extreme two-dimensional (2D) limit remains underexplored, despite theoretical predictions of exotic behavior. In particular, synthesis and atomic-scale characterization of ultrathin ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ films remain challenging. Here we explore molecular beam epitaxy grown ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ thin films down to a single-layer thickness. Structural characterization via electron and x-ray diffraction, atomic force microscopy, and scanning tunneling microscopy confirms layer-by-layer growth and high crystallinity, while magnetotransport measurements show the expected magnetic signatures. Interestingly, scanning tunneling microscopy and quasiparticle interference imaging reveal Dirac-like surface states that persist even in monolayer films and monolayer islands. Our experiments provide elusive atomic-scale insights into the band structure of ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ in the 2D limit and under lateral confinement, and establish a foundation for the synthesis of heterostructures based on monolayer ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ and device applications.

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Publication Details

Journal
Physical Review Materials
Published
2026-07-27
DOI
https://doi.org/10.1103/zmzs-krb9
Primary Topic
Topological Materials and Phenomena
Type
article
Field-Weighted Citation Impact
0.00

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Monolayer <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>MnBi</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi>Te</mml:mi> <mml:mn>4</mml:mn> </mml:msub> </mml:mrow> </mml:math> : Atomic-scale insigh

Hengxin Tan, Ilija Zeljkovic, Binghai Yan, Alexander LaFleur et al.
Physical Review Materials
Topological Materials and Phenomena
article

Monolayer <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>MnBi</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi>Te</mml:mi> <mml:mn>4</mml:mn> </mml:msub> </mml:mrow> </mml:math> : Atomic-scale insigh

Hengxin Tan, Ilija Zeljkovic, Binghai Yan, Alexander LaFleur, Siyuan Ding, Vsevolod Belosevich, Wilber Alfaro Castro, Zumeng Huang, Qiong Ma, Muxian Xu
article en

Abstract

As the first intrinsic antiferromagnetic topological insulator, ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ offers a platform for investigating topological phenomena driven by magnetism. Prior studies focused on bulk single crystals and exfoliated flakes, but the extreme two-dimensional (2D) limit remains underexplored, despite theoretical predictions of exotic behavior. In particular, synthesis and atomic-scale characterization of ultrathin ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ films remain challenging. Here we explore molecular beam epitaxy grown ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ thin films down to a single-layer thickness. Structural characterization via electron and x-ray diffraction, atomic force microscopy, and scanning tunneling microscopy confirms layer-by-layer growth and high crystallinity, while magnetotransport measurements show the expected magnetic signatures. Interestingly, scanning tunneling microscopy and quasiparticle interference imaging reveal Dirac-like surface states that persist even in monolayer films and monolayer islands. Our experiments provide elusive atomic-scale insights into the band structure of ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ in the 2D limit and under lateral confinement, and establish a foundation for the synthesis of heterostructures based on monolayer ${\mathrm{MnBi}}_{2}{\mathrm{Te}}_{4}$ and device applications.

Physical Review MaterialsVol. 10(7)
Boston College (US), Pennsylvania State University (US), Shanghai Jiao Tong University (CN)
U.S. Department of Energy
Openalex Percentile: Top 11%
Topological Materials and Phenomena
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