Ion abundances in the plasma tail of 3I/ATLAS show that it is N2-rich

Abstract Interstellar objects allow us to compare the early planetary formation process in the Solar System and around other stars. The second and third interstellar objects, 2I/Borisov and 3I/ATLAS, showed visible signs of activity, making it possible to assess their composition via spectroscopic analysis of their gas coma. While neutral volatiles surrounding comets are easily probed by common spectrographs, ion emissions emanate mostly from the tail, making them easier to detect with integral-field units. We present WHT/WEAVE-LIFU observations of 3I/ATLAS, performed post-perihelion on 2025 November 30 and 2025 December 02. We simultaneously detect the ions N2+, CO+, CO2+, H2O+ and CH+ located in an anti-solar tail. Using common fluorescence factors, we determine abundance ratios of these species in the tail. In particular, the N2+/CO+ ratio allows us to constrain the lower-limit N2/CO>0.023 ±0.001, indicating that 3I/ATLAS is N2-rich compared to Solar System comets, a property which can be linked to cold formation conditions. Abundance ratios between other ions cannot directly be used to constrain abundances of neutrals but seem consistent with the fact that 3I/ATLAS is enriched in hypervolatiles. We also investigate whether these ratios vary along the tail, and only detect a marginal decrease of CH+ with cometocentric distance.