Thiylation Products of 2(5H)-Furanone Derivatives with 2,2'-Oxydiethanethiol
Abstract The reactivity of mucochloric acid and its 5-substituted derivatives towards 2,2'-oxydiethanethiol was studied. A specific feature of the reaction of mucochloric acid with 2,2'-oxydiethanethiol carried out in the presence of triethylamine was revealed. Compared to previously studied reactions with aliphatic dithiols, minor products of the lactone ring degradation, possessing a propenal fragment, were also isolated in this reaction, along with a bis-thioether of the 2(5H)-furanone series. A series of novel bis-thioethers and thiols containing an unsaturated γ-lactone ring and a dithiol fragment were synthesized and characterized.
Authors
- О.А. Lodochnikova (ORCID: https://orcid.org/0000-0001-9614-5092)
- E. S. Rabbanieva (ORCID: https://orcid.org/0000-0002-7963-2814)
- Alsu M. Khabibrakhmanova (ORCID: https://orcid.org/0000-0001-7525-0133)
- Almira R. Kurbangalieva (ORCID: https://orcid.org/0000-0002-2436-7427)
- D. P. Gerasimova (ORCID: https://orcid.org/0000-0001-9770-196X)
- Lien T. Hoang (ORCID: https://orcid.org/0009-0007-1235-3718)
- Margarita Yu. Kuzmicheva (ORCID: https://orcid.org/0009-0008-8325-655X)
Institutions
- Kazan Federal University (RU)
- A.E. Arbuzov Institute of Organic and Physical Chemistry (RU)
Publication Details
- Journal
- Russian Journal of General Chemistry
- Published
- 2026-07-23
- DOI
- https://doi.org/10.1134/s1070363226602309
- Primary Topic
- Organic Chemistry Synthesis Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00