Assessing Seawater Intrusion in a Multilayer Gulf Coast Aquifer System Using Hydrogeochemical–Isotopic Evidence and SEAWAT

Seawater intrusion (SWI) increasingly threatens coastal aquifers that serve growing communities, emphasizing the need for generalizable, process-based diagnostics. We evaluate SWI in a multilayer coastal aquifer system in southern Alabama, USA, by integrating three groundwater sampling campaigns during spring–early summer 2025 (March, April, and June), hydrogeochemical–isotopic analyses, and variable-density SEAWAT modeling. This study couples HFE–Gibbs–isotope diagnostics with hydraulic-head-constrained SEAWAT modeling to characterize seawater intrusion extent and process state in a multilayer coastal setting. Groundwater major ions and δ18O/δ2H indicate dominantly meteoric, rock-weathering waters (Ca–HCO3 inland) with localized Na–Cl near the coast; most samples plot in the rock dominance field, and stable isotope values cluster near the meteoric water line. A 3-D SEAWAT model (seven layers, 150 × 150 m cells), calibrated to available groundwater head observations using PEST, indicates that modeled intrusion is concentrated at depth in confined Miocene units, whereas shallow groundwater sampled from the unconfined zone remains largely fresh based on hydrogeochemical and isotopic evidence. Because chloride observations were used primarily for interpretation rather than direct transport calibration, the modeled deep salinity distribution is treated as a process-based estimate rather than a uniquely calibrated chloride field. To quantify exposure and process state, we introduce two indicators: a Depth-Weighted Intrusion Index (DWII) integrating the extent and intensity of the transition zone across layers, and an Ion-Exchange Departure Index (IEDI) capturing normalized Na–Cl departures from conservative mixing due to cation exchange. Predominantly negative IEDI values indicate reverse exchange with weaker intensity during spring freshening and only localized forward exchange episodes. Beyond the site-specific findings, the DWII and IEDI introduced in this study provide practical tools for detecting and quantifying subtle seawater intrusion in low-salinity coastal aquifers and may be applicable to other coastal aquifer systems with similar hydrogeological settings.