Cross-Code Verification for Improved Thermophysical Properties of Argon, Krypton and Xenon Plasmas

Thermophysical properties of thermal plasmas are essential input data for computational models. The required data are usually taken from the literature without examination of their reliability. Cross-code verifications of properties are rare in the thermal plasma literature, partly due to the complexity of the calculation methods, which require a systematic treatment of large datasets, multiple computations and the adoption of different models. Here, a detailed comparison of two computational codes that use different workflows but very similar underlying methods is presented, using the example of thermophysical properties of argon, krypton, and xenon plasmas in local thermodynamic equilibrium at pressures from 1 to 100 atm. The comparison considers plasma composition, collision integrals, thermodynamic properties and, in particular, transport coefficients. The comparison allowed inconsistencies and errors to be identified and corrected, resulting in improved thermophysical properties of argon, krypton, and xenon. Furthermore, transport coefficients obtained from state-of-the-art intermolecular potentials were compared with those obtained from the simpler phenomenological potential, demonstrating good agreement, including at high pressures.