Quantum Wave Packet Study of the O( <sup>3</sup> P) + DBr → OD + Br Reaction: Cross Sections, Rate Constants, and Initial State Dependences
P) + DBr system suggests the influence of tunneling. Isotopic substitution of H by D significantly reduces both ICSs at low energies and RCs across the entire temperature range (100-800 K), with differences of up to 2 orders of magnitude at low temperatures due to the large disparity in tunneling ability between the two systems.
Authors
- Shi Ying Lin (ORCID: https://orcid.org/0000-0001-9395-5321)
Institutions
- Shandong University (CN)
Publication Details
- Journal
- The Journal of Physical Chemistry A
- Published
- 2026-07-22
- DOI
- https://doi.org/10.1021/acs.jpca.6c02329
- Primary Topic
- Advanced Chemical Physics Studies
- Type
- article
- Field-Weighted Citation Impact
- 0.00