Occurrence and Levels of Glyphosate, Chlorate and Perchlorate in Irish Drinking Water: A Pilot Study

ABSTRACT Safe drinking water is a crucial component of public health. Pesticides and disinfection byproducts are known pollutants of concern. This study aimed to investigate the levels of the herbicide glyphosate and disinfection byproducts in Irish drinking water. Drinking water samples ( N = 72) were analysed for glyphosate and its metabolite, using high‐performance liquid chromatography with mass spectrometry (LOQ 0.04 μg/L) and chlorate and perchlorate using ion chromatography with mass spectrometry (LOQ 0.1 μg/L). Glyphosate and AMPA were not detected in any sample. The detection rates for chlorate and perchlorate were 81.9% and 2.8%, respectively. One sample (1.4%) exceeded the WHO guidance level of 700 μg/L for chlorates, and eight samples (11.1%) exceeded the upcoming EU drinking water guidance value of 250 μg/L. These results generated novel data, although the sample size was limited. With some samples exceeding the recommended guidance values, it emphasises the need for future research.

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Publication Details

Journal
Water and Environment Journal
Published
2026-07-17
DOI
https://doi.org/10.1111/wej.70078
Primary Topic
Chemical Analysis and Environmental Impact
Type
article
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article

Occurrence and Levels of Glyphosate, Chlorate and Perchlorate in Irish Drinking Water: A Pilot Study

Alison Connolly, Marie A. Coggins, Jim Garvey, Sewon Lee
Water and Environment Journal
Chemical Analysis and Environmental Impact
article

Occurrence and Levels of Glyphosate, Chlorate and Perchlorate in Irish Drinking Water: A Pilot Study

Alison Connolly, Marie A. Coggins, Jim Garvey, Sewon Lee
article en

Abstract

ABSTRACT Safe drinking water is a crucial component of public health. Pesticides and disinfection byproducts are known pollutants of concern. This study aimed to investigate the levels of the herbicide glyphosate and disinfection byproducts in Irish drinking water. Drinking water samples ( N = 72) were analysed for glyphosate and its metabolite, using high‐performance liquid chromatography with mass spectrometry (LOQ 0.04 μg/L) and chlorate and perchlorate using ion chromatography with mass spectrometry (LOQ 0.1 μg/L). Glyphosate and AMPA were not detected in any sample. The detection rates for chlorate and perchlorate were 81.9% and 2.8%, respectively. One sample (1.4%) exceeded the WHO guidance level of 700 μg/L for chlorates, and eight samples (11.1%) exceeded the upcoming EU drinking water guidance value of 250 μg/L. These results generated novel data, although the sample size was limited. With some samples exceeding the recommended guidance values, it emphasises the need for future research.

Water and Environment Journal
University College Dublin (IE), Ollscoil na Gaillimhe – University of Galway (IE), Department of Agriculture Food and the Marine (IE)
Clean water and sanitation
Openalex Percentile: Top 9%
Chemical Analysis and Environmental Impact
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Occurrence and Levels of Glyphosate, Chlorate and Perchlorate in Irish Drinking Water: A Pilot Study — Alison Connolly, Marie A. Coggins, et al. · Water and Environment Journal (2026) | TGRS Research Map | TGRS