Mechanical and Spectrophotometric Properties of Nano-WS2 Modified PVB/Epoxy Coatings on Glass

The development of transparent multifunctional coatings capable of combining optical properties with mechanical durability remains a significant challenge in advanced materials engineering. In this study, novel hybrid coatings based on a poly(vinyl butyral)/epoxy resin (PVB/epoxy) matrix reinforced with tungsten disulfide (WS2) nanostructures were developed and examined for potential application in camouflage protection of glass surfaces. Camouflage aims to reduce the detectability of an object by minimizing the optical contrast between the object and its surrounding environment. For transparent substrates such as glass, this objective is particularly demanding because the transparency must be preserved while reducing unwanted surface reflection and optical signatures over relevant spectral ranges. For this purpose, in this research two types of nanostructures were investigated: fullerene-like nanoparticles (IF-WS2) and inorganic nanotubes (INT-WS2). The coatings were fabricated via ultrasonically assisted solution dispersion followed by casting over the glass plates and Teflon molds, and solvent evaporation. Structural, thermal, optical, and mechanical properties were systematically evaluated using SEM, FTIR, DSC, UV-Vis-NIR spectroscopy, gloss measurements, hardness testing, and cavitation wear resistance analysis. The incorporation of WS2 nanostructures led to improved mechanical performance, with increased hardness and enhanced resistance to cavitation-induced wear. Optical characterization showed moderate reductions in reflectance and controlled transmittance in the visible and near-infrared regions, while overall transparency was maintained. The results indicate that WS2 nanostructures contribute to both light scattering and absorption, leading to reduced specular reflection and improved optical masking potential. The findings demonstrate that hybrid PVB/epoxy/WS2 coatings offer a promising approach for designing transparent, mechanically resistant coatings with tunable optical properties, with potential applications in protective glass systems and advanced functional surfaces.