Mineralogical Characterization of a Typical Gray Siliceous Concretion on Marine-Excavated Ceramics from the Nanhai No. 1 Shipwreck: A Multi-Analytical Case Study

Gray siliceous concretions represent the most ubiquitous surface deposits on marine-excavated ceramics from the Nanhai No. 1 shipwreck. These concretions obscure decorative motifs and glaze surfaces of the artifacts, posing challenges to archeological interpretation and heritage conservation. This study conducted a multi-technique characterization of one representative gray siliceous concretion using micro-CT, PLM, SEM-EDS, XRD, FTIR, and micro-Raman spectroscopy. The concretion exhibits distinct three-tier density stratification and consists of quartz, muscovite, calcite, pyrite, and Mg-rich authigenic silicates (serpentine and talc), with quartz and muscovite as the dominant crystalline phases. Its mineral components are inferred to originate from terrigenous clastic, biogenic, and authigenic sources. This work provides fundamental mineralogical data to support the development of targeted conservation strategies for analogous marine-excavated ceramic heritage.