Rapid Processing of Silk Nanofibril Membranes for Molecule Rejection and Gas Barrier

A one-step, efficient alkali hydrolysis method was established to mildly exfoliate silk nanofibrils (SNFs) from natural silkworm cocoons on a large scale. The as-prepared SNFs showed an excellent dispersity and stability in various solvents. Two kinds of SNF membranes (i.e., mesoporous and nanoporous membranes) with controlled pore structures were fabricated and functioned for selective interception and protection properties, respectively. The SNF mesoporous membranes were efficient as rejection membranes, while the SNF nanoporous membranes revealed relatively high gas-barrier properties. This work offers a facile and green route for fabricating SNF-based functional-membrane materials and expanding their potential applications in filtration and gas-barrier domains.

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Publication Details

Journal
ACS Applied Polymer Materials
Published
2026-07-01
DOI
https://doi.org/10.1021/acsapm.6c01645
Primary Topic
Supramolecular Self-Assembly in Materials
Type
article
Field-Weighted Citation Impact
0.00

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article

Rapid Processing of Silk Nanofibril Membranes for Molecule Rejection and Gas Barrier

Chaoxu Li, Zehui Li, Xiaochen Wu, R Y Wang et al.
ACS Applied Polymer Materials
Supramolecular Self-Assembly in Materials
article

Rapid Processing of Silk Nanofibril Membranes for Molecule Rejection and Gas Barrier

Chaoxu Li, Zehui Li, Xiaochen Wu, R Y Wang, Xiangsheng Han, Lili Lv, Xihui Zhao, Li M, Minghao Mu
article en

Abstract

A one-step, efficient alkali hydrolysis method was established to mildly exfoliate silk nanofibrils (SNFs) from natural silkworm cocoons on a large scale. The as-prepared SNFs showed an excellent dispersity and stability in various solvents. Two kinds of SNF membranes (i.e., mesoporous and nanoporous membranes) with controlled pore structures were fabricated and functioned for selective interception and protection properties, respectively. The SNF mesoporous membranes were efficient as rejection membranes, while the SNF nanoporous membranes revealed relatively high gas-barrier properties. This work offers a facile and green route for fabricating SNF-based functional-membrane materials and expanding their potential applications in filtration and gas-barrier domains.

ACS Applied Polymer Materials
Qingdao University (CN), Creative Technology (Singapore) (SG), Qingdao University of Science and Technology (CN), Shanghai Jiao Tong University (CN), Jianghan University (CN), Culture Resource (EG), Marine Biology Institute of Shandong Province (CN), Qingdao Institute of Bioenergy and Bioprocess Technology (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 15%
Supramolecular Self-Assembly in Materials
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Rapid Processing of Silk Nanofibril Membranes for Molecule Rejection and Gas Barrier — Chaoxu Li, Zehui Li, et al. · ACS Applied Polymer Materials (2026) | TGRS Research Map | TGRS