Mechanical Performance Investigation of Recycled HDPE Reinforced with Nanoclay for Enhanced Strength and Sustainability

The increasing demand for sustainable materials has intensified efforts to enhance the performance of recycled polymers for engineering applications. This study investigates the effect of nanoclay reinforcement on the mechanical properties of recycled high-density polyethylene (rHDPE). Nanoclay was incorporated into rHDPE at varying loadings through melt blending, and the resulting composites were evaluated in terms of tensile, flexural, impact, and hardness properties. The tensile strength and tensile modulus improved significantly with increasing nanoclay content, reaching maximum values of 31.27 MPa and 2.39 GPa, respectively, at 1.5 wt% nanoclay, corresponding to increases of 23.11% and 47.53% relative to unreinforced rHDPE. Similarly, the flexural strength and flexural modulus attained peak values of 25.88 MPa and 1105.08 MPa at 1.5 wt% nanoclay, representing improvements of 12.57% and 15.49%, respectively. Impact strength exhibited a different trend, achieving a maximum value of 73.58 kJ/m2 at 0.5 wt% nanoclay before decreasing at higher loadings, indicating a transition towards more brittle behaviour. Hardness increased progressively with nanoclay addition and reached a maximum value of 68.06 Shore D at 1.5 wt%, exceeding both unreinforced rHDPE and virgin HDPE. The overall results demonstrate that nanoclay effectively compensates for the mechanical degradation associated with recycling by enhancing stiffness, strength, and surface hardness. Among the investigated formulations, 1.5 wt% nanoclay provided the optimum balance of mechanical performance, while higher loadings led to reduced reinforcement efficiency due to particle agglomeration. These findings highlight the potential of nanoclay-reinforced rHDPE as a sustainable, high-performance material for applications in packaging, construction, and automotive components, thereby supporting circular economy initiatives and resource-efficient material development.

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Publication Details

Journal
Polymers
Published
2026-06-29
DOI
https://doi.org/10.3390/polym18131615
Primary Topic
Natural Fiber Reinforced Composites
Type
article
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article

Mechanical Performance Investigation of Recycled HDPE Reinforced with Nanoclay for Enhanced Strength and Sustainability

Sundarakannan Rajendran, Koppiahraj Karuppiah, Magdalena Niemczewska-Wójcik, Geetha Palani et al.
Polymers
Natural Fiber Reinforced Composites
article

Mechanical Performance Investigation of Recycled HDPE Reinforced with Nanoclay for Enhanced Strength and Sustainability

Sundarakannan Rajendran, Koppiahraj Karuppiah, Magdalena Niemczewska-Wójcik, Geetha Palani, S. Thirumalai Kumaran, Sakthivel Sankaran, Udayakumar Marimuthu
article en

Abstract

The increasing demand for sustainable materials has intensified efforts to enhance the performance of recycled polymers for engineering applications. This study investigates the effect of nanoclay reinforcement on the mechanical properties of recycled high-density polyethylene (rHDPE). Nanoclay was incorporated into rHDPE at varying loadings through melt blending, and the resulting composites were evaluated in terms of tensile, flexural, impact, and hardness properties. The tensile strength and tensile modulus improved significantly with increasing nanoclay content, reaching maximum values of 31.27 MPa and 2.39 GPa, respectively, at 1.5 wt% nanoclay, corresponding to increases of 23.11% and 47.53% relative to unreinforced rHDPE. Similarly, the flexural strength and flexural modulus attained peak values of 25.88 MPa and 1105.08 MPa at 1.5 wt% nanoclay, representing improvements of 12.57% and 15.49%, respectively. Impact strength exhibited a different trend, achieving a maximum value of 73.58 kJ/m2 at 0.5 wt% nanoclay before decreasing at higher loadings, indicating a transition towards more brittle behaviour. Hardness increased progressively with nanoclay addition and reached a maximum value of 68.06 Shore D at 1.5 wt%, exceeding both unreinforced rHDPE and virgin HDPE. The overall results demonstrate that nanoclay effectively compensates for the mechanical degradation associated with recycling by enhancing stiffness, strength, and surface hardness. Among the investigated formulations, 1.5 wt% nanoclay provided the optimum balance of mechanical performance, while higher loadings led to reduced reinforcement efficiency due to particle agglomeration. These findings highlight the potential of nanoclay-reinforced rHDPE as a sustainable, high-performance material for applications in packaging, construction, and automotive components, thereby supporting circular economy initiatives and resource-efficient material development.

PolymersVol. 18(13)
Vel Tech Rangarajan Dr. Sagunthala R&D Institute of Science and Technology (IN), Chennai Mathematical Institute (IN), Cracow University of Technology (PL), PSG INSTITUTE OF TECHNOLOGY AND APPLIED RESEARCH (IN), Amrita Vishwa Vidyapeetham (IN), Kalasalingam Academy of Research and Education (IN)
Industry, innovation and infrastructure
Openalex Percentile: Top 15%
Natural Fiber Reinforced Composites
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