Thermoelectric PANI/TeNWs Fiber Based Microsensor for Passive Temperature and Active Chemical Sensing

ABSTRACT Micrometer‐scale chemical sensors serve as pivotal functional components that bridge microscopic environments and macroscopic information systems, yet integrating multiple sensing modalities within a single microscale fiber without compromising performance remains a challenge in materials design. Herein, we report a continuous wet‐spinning process to fabricate multifunctional microfibers that integrate chemically responsive polyaniline (PANI) with high‐Seebeck‐coefficient tellurium nanowires (TeNWs). The optimized PANI/TeNWs composite fiber (60 wt.% TeNWs) achieves a Seebeck coefficient of 59.9 µV K −1 and a power factor of 9.2 µW m −1 K −2 , enabling passive temperature monitoring with a detection limit of 1 K, where thermal gradients directly generate the sensing signal. Simultaneously, the fiber demonstrates remarkable chemical sensing capabilities, exhibiting a Nernstian pH response (59.25 mV pH −1 ) and rapid ammonia detection (0.96 s at 50 ppm). By demonstrating both passive thermoelectric transduction and active chemical sensing in a single microfiber platform, this work establishes a versatile material system that combines energy‐autonomous temperature sensing with high‐performance chemical detection. This integrated approach offers substantial application prospects in precision medicine and environmental safety monitoring, where miniaturized sensors with diverse functionalities are urgently needed.