Reactivity Studies on the Terminal Thorium Imido Metallocene (η <sup>5</sup> -C <sub>5</sub> Me <sub>5</sub> ) <sub>2</sub> Th(═Ndipp)(dmap)
) is isolated in the presence of AgI. Furthermore, a comparison with related terminal imido thorium metallocene derivatives demonstrates nicely how different substituents on the cyclopentadienyl and imido ligands influence the reactivity of these compounds.
Authors
- Marc D. Walter (ORCID: https://orcid.org/0000-0002-4682-8749)
- Guohua Hou (ORCID: https://orcid.org/0000-0002-3571-456X)
- Wanjian Ding (ORCID: https://orcid.org/0000-0002-4970-5816)
- Guofu Zi (ORCID: https://orcid.org/0000-0002-7455-460X)
- Yi Heng
- Xiaoying Cao
Institutions
- Beijing Normal University (CN)
- Technische Universität Braunschweig (DE)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-06-28
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c01355
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Deutsche Forschungsgemeinschaft
- National Natural Science Foundation of China