Occurrence, Sources, and Ecological Risks of Organochlorine Pesticides in Sediments of Typical Plateau Lakes, Southwest China

This study investigated the contamination characteristics, sources, and ecological risks of organochlorine pesticides (OCPs) in surface sediments from three plateau lakes in southwestern China (Qilu Lake, Dianchi Lake, and Yangzonghai Lake). Significant differences in OCP pollution levels were observed among the three lakes. Hexachlorocyclohexanes (HCHs) were identified as the dominant contaminants, reflecting historical technical HCH input and subsequent long-term aging, whereas dichlorodiphenyltrichloroethanes (DDTs) exhibited generally low concentrations and originated primarily from historical technical use, with predominantly aerobic degradation. Principal component analysis (PCA) revealed that agricultural non-point source pollution was the main contributor to OCP residues. Ecological risk assessment demonstrated that most OCPs posed low or negligible risk; however, γ-HCH (lindane) ubiquitously presented moderate risk across all lakes, with one site exceeding the high-risk threshold. Endrin derivatives and methoxychlor further elevated combined risks at specific sites. Notably, the unique hydrological characteristics of plateau lakes may enhance OCP retention and accumulation in sediments. These findings provide a scientific basis for ecological risk management and pollution control in plateau lakes.