Dioxocobaltate(II) Anions in Alkaline Earth–Lanthanum Germanate Apatites: Magnetic Anisotropy and Correlated Dual Slow Relaxation of Magnetization
values correspond to certain Co-O distances in the spin-only state. The distances follow a qualitative relation with estimated Coulomb forces acting between ions in the host compound. These findings suggest that to convert the dioxocobaltate(II) anion into the desired non-Aufbau state, one must construct a host apatite crystal from ions with lower charges and larger sizes.
Authors
- Reinhard K. Kremer (ORCID: https://orcid.org/0000-0001-9062-2361)
- Pavel E. Kazin (ORCID: https://orcid.org/0000-0002-1415-2190)
- Timur Z. Sharifullin (ORCID: https://orcid.org/0000-0002-6879-2951)
- А. А. Елисеев (ORCID: https://orcid.org/0000-0002-2851-6821)
- Robert E. Dinnebier (ORCID: https://orcid.org/0000-0003-2778-2113)
- Alexander V. Vasiliev (ORCID: https://orcid.org/0000-0003-4108-9040)
- Artem A. Shevchenko
- Zakhar A. Zaitsev
Institutions
- Lomonosov Moscow State University (RU)
- Max Planck Institute for Solid State Research (DE)
- Moscow State University (TJ)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-06-17
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c01848
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Ministry of Education and Science of the Russian Federation