GaN/Sn:Ga <sub>2</sub> O <sub>3</sub> @MgO/Graphene Core–Shell Nanowires for Self-Powered Deep-UV Photodetector

To address high dark current and surface defects in β-Ga 2 O 3 nanowire (NW) photodetectors, we report a multilayered core–shell heterostructure based on GaN/Sn:Ga 2 O 3 @MgO/graphene. Sn-doped Ga 2 O 3 NW arrays were grown via CVD on GaN substrates, followed by thermal evaporation of an MgO passivation shell and spin-coating of graphene. The MgO shell suppresses surface-state recombination and facilitates carrier separation through band bending, while the graphene layer optimizes carrier-transport paths and energy-level matching. Under 254 nm illumination (82 μW/cm 2 ), the device exhibits outstanding performance: a low dark current of 85.6 pA, a high PDCR of 2.13 × 10 4, a responsivity of 0.71 A/W, and a specific detectivity ( D *) of 2.40 × 10 13 Jones. This synergistic architecture provides a robust strategy for high-performance deep-ultraviolet (DUV) detection.

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Publication Details

Journal
ACS Applied Nano Materials
Published
2026-06-17
DOI
https://doi.org/10.1021/acsanm.6c01763
Primary Topic
Ga2O3 and related materials
Type
article
Field-Weighted Citation Impact
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GaN/Sn:Ga 2 O 3 @MgO/Graphene Core–Shell Nanowires for Self-Powered Deep-UV Photodetector

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GaN/Sn:Ga 2 O 3 @MgO/Graphene Core–Shell Nanowires for Self-Powered Deep-UV Photodetector

Wenqiang Lu, Bohan Zhang, Yubin Liu, Siyi He, Muhammad Abdul Salam, Zhiyang He, Jingpeng Tan, S M Yang, Chengming Jiang
article en

Abstract

To address high dark current and surface defects in β-Ga 2 O 3 nanowire (NW) photodetectors, we report a multilayered core–shell heterostructure based on GaN/Sn:Ga 2 O 3 @MgO/graphene. Sn-doped Ga 2 O 3 NW arrays were grown via CVD on GaN substrates, followed by thermal evaporation of an MgO passivation shell and spin-coating of graphene. The MgO shell suppresses surface-state recombination and facilitates carrier separation through band bending, while the graphene layer optimizes carrier-transport paths and energy-level matching. Under 254 nm illumination (82 μW/cm 2 ), the device exhibits outstanding performance: a low dark current of 85.6 pA, a high PDCR of 2.13 × 10 4, a responsivity of 0.71 A/W, and a specific detectivity ( D *) of 2.40 × 10 13 Jones. This synergistic architecture provides a robust strategy for high-performance deep-ultraviolet (DUV) detection.

ACS Applied Nano Materials
Chongqing University of Posts and Telecommunications (CN), Beijing Founder Electronics (China) (CN), Chongqing Institute of Green and Intelligent Technology (CN), University of Chinese Academy of Sciences (CN)
Affordable and clean energy
Openalex Percentile: Top 17%
Ga2O3 and related materials
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