Study on the Preparation and Mechanism of High–Modulus Polyurethane Prepolymer (HM–PU)–Modified Bitumen

This study aims to solve the problems of the high carbon emissions, poor compatibility, and insufficient storage stability of conventional polymer–modified bitumen (PMB). A novel High–Modulus Polyurethane Prepolymer (HM–PU) bitumen modifier was independently prepared to explore its modification effect and optimal application parameters. Experimental results show that the optimal isocyanate group (NCO) content and dosage of the HM–PU modifier are both 5%. The thermal stability and high– and low–temperature performance of modified bitumen are significantly enhanced, and HM–PU exhibits excellent compatibility with base bitumen (BA). This work innovatively synthesizes the HM–PU modifier and clarifies its physicochemical modification mechanism via macroscopic performance tests, thermal analysis, and microscopic characterization, providing a new strategy for the development and application of eco–friendly bitumen modifiers.