Endo/On-Cage Boron Doping for Stabilization and Strong Magnetic Coupling in Metallofullerenes Gd<sub>2</sub>@C<sub>80</sub> and Gd<sub>3</sub>@C<sub>80</sub>.
as calculated by BS-DFT. Our findings demonstrate that endo/on-cage boron doping is an effective strategy to stabilize redox-active Gd-based metallofullerenes and engineer strong magnetic coupling. The discovery of the 3c-1e bond in trimetallofullerenes opens up new possibilities for the design and construction of diverse high-performance molecular magnetic materials.
Authors
- Zhaohan Lu (ORCID: https://orcid.org/0000-0003-3610-7371)
- Zhiyong Wang
Institutions
- Renmin University of China (CN)
Publication Details
- Journal
- PubMed
- Published
- 2026-06-29
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c01663
- Primary Topic
- Fullerene Chemistry and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00