Study on Properties and Hydration Mechanism of Polymer-Modified High-Belite Sulfoaluminate Cement Repair Mortar

In this study, the rapidly setting and hardening high-belite sulfoaluminate cement (HBSAC) is used as the cementitious material, with natural river sand as the fine aggregate, and a high-performance repair mortar is prepared through the synergistic use of different polymers and admixtures. The influences of two polymers (VAE and HPMC) on the working performance, mechanical properties, and hydration characteristics of HBSAC mortars are systematically studied. The results showed that the two polymers had a significant improvement effect on the setting time, mortar flowability, and water retention rate of HBSAC mortar. Among them, VAE had a significant effect on the mortar flowability, and a 5% content could increase the flowability of HBSAC mortar by 29.8%. HPMC has a significant improvement effect on setting time and water retention rate; at 0.1% content, it can delay the initial setting time by 6.5 min and achieve a water retention rate of over 90%. As the polymer to binder ratio increases, both polymers, except for 2.5% VAE, which can slightly improve the flexural strength of mortar, will reduce the flexural and compressive strength of mortar, with VAE causing greater damage to strength. On the contrary, the polymer significantly enhanced the bond strength of the mortar. Compared with the cement control group, the 28 d bond strength of 5% VAE and 0.1% HPMC groups increased by 56.7% and 15.1%, respectively. Moreover, the addition of polymers delayed the occurrence of the exothermic peaks of HBSAC dissolution and ettringite formation, but the total amount of hydration heat released within 48 h was higher than that of pure cement. The diffraction peaks of AFt in the hydration products of VAE-HBSAC paste at 3d and 28d showed significant enhancement, and the peak intensity increased with higher doping levels, while the diffraction peak intensity of C2S showed a certain decrease. The polymer significantly increased the weight loss peak intensity and mass loss after heating of AFt, AH3, AFm, and C-S-H gel. The SEM images indicate that VAE can form a mesh on the surface of hydration products and refine the crystal size of AFt; HPMC wraps more flocculent substances around the hydration products, thereby improving the compactness of paste. This study can provide scientific reference for improving the performance and promoting the practical application of high-performance rapid repair mortar for concrete structure damage.