Crystallography of periodic nanotextures in a strained Mott insulator

Here we investigate stripes of alternating structural phases spontaneously forming in epitaxially strained $Ca_2RuO_4$ thin films below the metal-insulator transition. Using large-volume X-ray reciprocal-space mapping, we show that satellite-pattern intensities across 24 symmetry-inequivalent Bragg reflections collapse onto a single parameter-free curve. The collapse identifies a coherent martensitic laminate of few-nm-wide domains separated by ${012}$ interfaces, with displacements along $\left\langle01\bar{2}\right\rangle$. Satellite-extinction analysis demonstrates that both coexisting phases retain the bulk orthorhombic space group despite the pseudocubic $LaAlO_3$ substrate, biaxial epitaxial strain, and intrinsic strain at the interfaces. Classical invariant-plane-strain crystallography thus governs the nanoscale domain geometry of a Mott insulator with intertwined magnetic, electronic, and lattice order.

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Publication Details

Journal
Physical Review Letters
Published
2026-10-28
DOI
https://doi.org/10.1103/kmws-wh4q
Primary Topic
Electronic and Structural Properties of Oxides
Type
article
Field-Weighted Citation Impact
0.00

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article

Crystallography of periodic nanotextures in a strained Mott insulator

Suchismita Sarker, Yorick A. Birkhölzer, Ziming Shao, Noah Schnitzer et al.
1 links
Physical Review Letters
Electronic and Structural Properties of Oxides
article

Crystallography of periodic nanotextures in a strained Mott insulator

Suchismita Sarker, Yorick A. Birkhölzer, Ziming Shao, Noah Schnitzer, Benjamin Z. Gregory, Andrej Singer, K. M. Shen, Darrell G. Schlom, Berit Hansen Goodge, Jacob P. Ruff, Jeffrey W Hodgson, David A. Muller
article en

Abstract

Here we investigate stripes of alternating structural phases spontaneously forming in epitaxially strained $Ca_2RuO_4$ thin films below the metal-insulator transition. Using large-volume X-ray reciprocal-space mapping, we show that satellite-pattern intensities across 24 symmetry-inequivalent Bragg reflections collapse onto a single parameter-free curve. The collapse identifies a coherent martensitic laminate of few-nm-wide domains separated by ${012}$ interfaces, with displacements along $\left\langle01\bar{2}\right\rangle$. Satellite-extinction analysis demonstrates that both coexisting phases retain the bulk orthorhombic space group despite the pseudocubic $LaAlO_3$ substrate, biaxial epitaxial strain, and intrinsic strain at the interfaces. Classical invariant-plane-strain crystallography thus governs the nanoscale domain geometry of a Mott insulator with intertwined magnetic, electronic, and lattice order.

Physical Review Letters
National Science Foundation, U.S. Department of Energy, Gordon and Betty Moore Foundation, Division of Materials Research, Basic Energy Sciences
Openalex Percentile: Top 73%
Electronic and Structural Properties of Oxides
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Crystallography of periodic nanotextures in a strained Mott insulator — Suchismita Sarker, Yorick A. Birkhölzer, et al. · Physical Review Letters (2026) | TGRS Research Map | TGRS