Nickel-Catalyzed, Copper-Assisted Aromatic C–H Phosphinylation of [2.2]Paracyclophanes via Arylsulfonium Salts
-[2.2]paracyclophanylated products in good to excellent yields. The applicability of the present protocol was established through scalable preparation of the typical target product and its application as a potentially useful phosphine ligand for transition-metal-catalyzed carbene insertion to X-H (X = C, N) bonds.
Authors
- Liandi Wang (ORCID: https://orcid.org/0000-0003-4996-3687)
- Kaikai Wu (ORCID: https://orcid.org/0000-0003-1950-5343)
- Mingrui Li (ORCID: https://orcid.org/0000-0001-8348-1919)
- Ping Wu (ORCID: https://orcid.org/0000-0003-2650-9043)
- Zhengkun Yu (ORCID: https://orcid.org/0000-0002-9908-0017)
- Yong‐Gui Zhou (ORCID: https://orcid.org/0000-0002-3321-5521)
- Kaiyuan Yang (ORCID: https://orcid.org/0009-0000-0006-773X)
Institutions
- University of Science and Technology of China (CN)
- Dalian Institute of Chemical Physics (CN)
- Chinese Academy of Sciences (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2026-06-09
- DOI
- https://doi.org/10.1021/acs.orglett.6c02112
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China