An argument why the spinterface model cannot explain the chirality induced spin selectivity effect

In the context of chirality induced spin selectivity effect, it has been argued that a chiral molecule when adsorbed on a metal facilitates the formation of a local spin moment at the interface between the metal and molecule, given a strong spin-orbit coupling in the metal. The possibility for such spin moment formation is analyzed in terms of general arguments and effective modeling of a pertinent setup. The conclusion from this analysis is that a strong spin-orbit coupling in the metal does not provide a sufficient mechanism to sustain a stabilized spin moment at the interface. It is, moreover, shown that an electron flux into or out of the molecule does not provide conditions for a spin moment formation, regardless of whether the flux is spin-polarized or not.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2026-06-09
DOI
https://doi.org/10.1063/5.0337054
Primary Topic
Molecular Junctions and Nanostructures
Type
article
Field-Weighted Citation Impact
0.00

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article

An argument why the spinterface model cannot explain the chirality induced spin selectivity effect

Jonas Fransson
The Journal of Chemical Physics
Molecular Junctions and Nanostructures
article

An argument why the spinterface model cannot explain the chirality induced spin selectivity effect

Jonas Fransson
article en

Abstract

In the context of chirality induced spin selectivity effect, it has been argued that a chiral molecule when adsorbed on a metal facilitates the formation of a local spin moment at the interface between the metal and molecule, given a strong spin-orbit coupling in the metal. The possibility for such spin moment formation is analyzed in terms of general arguments and effective modeling of a pertinent setup. The conclusion from this analysis is that a strong spin-orbit coupling in the metal does not provide a sufficient mechanism to sustain a stabilized spin moment at the interface. It is, moreover, shown that an electron flux into or out of the molecule does not provide conditions for a spin moment formation, regardless of whether the flux is spin-polarized or not.

The Journal of Chemical PhysicsVol. 164(22)
Uppsala University (SE)
Stiftelsen Olle Engkvist Byggmästare
Openalex Percentile: Top 11%
Molecular Junctions and Nanostructures
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