Atomic Shell Structure and Vacuum Crystal Field Splitting on the Z3 ⊗ Q3 Discrete Lattice

Standard quantum mechanics derives the atomic principal shell capacities 2n2 and the subshell splittings 2(2ℓ+1) from the continuous SO(3) rotational symmetry and the acciden- tal SO(4) degeneracy of the 1/r Coulomb potential. We demonstrate that these capacities and degeneracies emerge natively from the bound-state eigenspectrum of a purely discrete information-routing lattice. The vacuum substrate is specified as a simple cubic lattice Z3 partitioned into a Q3 internal space of three space-filling oblate square bipyramids per cubic unit cell. Modelling the lepton sector colour-singlet condition as a strong internal mixing penalty, and binding the resulting colourless walker by an effective Coulomb poten- tial motivated by the discrete Laplacian’s Green’s function, we find that continuous SO(3) spherical harmonics fracture into the exact direct sums of Oh (cubic) irreducible representa- tions required to recover the s,p,d,f subshells. Cumulative bound-state spatial capacities of 1,4,9,16 emerge without further input. The discrete origin of the lattice generates a falsifiable signature: a residual cubic-symmetry-breaking displacement of Eg d-orbital com- ponents into shorter radial extent than their T2g partners, persistent even in completely free atoms.

Authors

Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2026-05-31
DOI
https://doi.org/10.5281/zenodo.20478661
Primary Topic
Quasicrystal Structures and Properties
Type
preprint
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
preprint

Atomic Shell Structure and Vacuum Crystal Field Splitting on the Z3 ⊗ Q3 Discrete Lattice

David Elliman
Zenodo (CERN European Organization for Nuclear Research)
Quasicrystal Structures and Properties
preprint

Atomic Shell Structure and Vacuum Crystal Field Splitting on the Z3 ⊗ Q3 Discrete Lattice

David Elliman
preprint en

Abstract

Standard quantum mechanics derives the atomic principal shell capacities 2n2 and the subshell splittings 2(2ℓ+1) from the continuous SO(3) rotational symmetry and the acciden- tal SO(4) degeneracy of the 1/r Coulomb potential. We demonstrate that these capacities and degeneracies emerge natively from the bound-state eigenspectrum of a purely discrete information-routing lattice. The vacuum substrate is specified as a simple cubic lattice Z3 partitioned into a Q3 internal space of three space-filling oblate square bipyramids per cubic unit cell. Modelling the lepton sector colour-singlet condition as a strong internal mixing penalty, and binding the resulting colourless walker by an effective Coulomb poten- tial motivated by the discrete Laplacian’s Green’s function, we find that continuous SO(3) spherical harmonics fracture into the exact direct sums of Oh (cubic) irreducible representa- tions required to recover the s,p,d,f subshells. Cumulative bound-state spatial capacities of 1,4,9,16 emerge without further input. The discrete origin of the lattice generates a falsifiable signature: a residual cubic-symmetry-breaking displacement of Eg d-orbital com- ponents into shorter radial extent than their T2g partners, persistent even in completely free atoms.

Zenodo (CERN European Organization for Nuclear Research)
Quasicrystal Structures and Properties
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.

Atomic Shell Structure and Vacuum Crystal Field Splitting on the Z3 ⊗ Q3 Discrete Lattice — David Elliman · Zenodo (CERN European Organization for Nuclear Research) (2026) | TGRS Research Map | TGRS