The effects of shock process and terrestrial weathering on mercury isotopes in meteorites

Abstract This study assesses mercury (Hg) concentrations and their isotopic compositions in Antarctic chondrites, desert chondrites, and drilled samples from the Jilin chondrite (H5). Desert chondrites show mercury concentrations between 2.2 ng g −1 and 156.8 ng g −1 , with δ 202 Hg ranging from −3.69‰ to 1.19‰. Δ 199 Hg and Δ 201 Hg vary from −0.23‰ to −0.02‰ and −0.2‰ to 0.02‰, respectively, showing a weak positive correlation among these parameters (slope 0.74 ± 0.24, R 2 = 0.46). These Hg concentrations and isotopic composition data of desert chondrites indicate that Hg in desert chondrites has been altered due to terrestrial processes in addition to evaporation loss during its terrestrial residence period. Antarctic chondrites exhibit mercury concentrations from 8.0 ng g −1 to 3940.8 ng g −1 , with δ 202 Hg from −2.51‰ to 1.16‰. Δ 199 Hg and Δ 201 Hg range from −0.83‰ to −0.05‰ and −0.71‰ to 0.10‰, with a significant correlation (slope 0.93 ± 0.15, R 2 = 0.76), likely influenced by Antarctic snow that has experienced significant photochemical processes during atmospheric mercury depletion events (AMDEs) and has elevated mercury content (such as drifted snow). Jilin meteorite's δ 202 Hg, Δ 199 Hg, and Δ 201 Hg vary between −3.74‰ to −1.79‰, −0.12‰ to 0.09‰, and −0.12‰ to −0.01‰, respectively. A weak positive correlation between Δ 199 Hg and Δ 201 Hg (slope 1.45 ± 0.28, R 2 = 0.67) suggests localized Hg evaporation due to shock processes on the parent body; however, Hg isotopic heterogeneity from nebular or parent body processes cannot be excluded. Terrestrial weathering and shock events could alter Hg content and isotopic compositions in chondrites, challenging their use as accurate indicators of Hg's cosmochemical behavior.