Unveiling the coupled tandem oxidative mechanism in CO2-assisted propane dehydrogenation over a ZnO-promoted VOX/SAPO-34 catalyst

• ZnO enriches oxygen vacancies, enhances reducibility, and strengthens CO 2 adsorption. • CTO mechanism revealed: propane couples with CO₂-derived oxygenates. • MD and microkinetic modeling confirm propylene amplification via C–C coupling.

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Publication Details

Journal
Journal of CO2 Utilization
Published
2026-05-27
DOI
https://doi.org/10.1016/j.jcou.2026.103473
Primary Topic
Catalysis and Oxidation Reactions
Type
article
Field-Weighted Citation Impact
0.00

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article

Unveiling the coupled tandem oxidative mechanism in CO2-assisted propane dehydrogenation over a ZnO-promoted VOX/SAPO-34 catalyst

Masoud Safari Yazd, Reza Asadi, Jafar Towfighi Darian
Journal of CO2 Utilization
Catalysis and Oxidation Reactions
article

Unveiling the coupled tandem oxidative mechanism in CO2-assisted propane dehydrogenation over a ZnO-promoted VOX/SAPO-34 catalyst

Masoud Safari Yazd, Reza Asadi, Jafar Towfighi Darian
article en

Abstract

• ZnO enriches oxygen vacancies, enhances reducibility, and strengthens CO 2 adsorption. • CTO mechanism revealed: propane couples with CO₂-derived oxygenates. • MD and microkinetic modeling confirm propylene amplification via C–C coupling.

Journal of CO2 UtilizationVol. 109
Tarbiat Modares University (IR)
Iran National Science Foundation
Openalex Percentile: Top 17%
Catalysis and Oxidation Reactions
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