Synthesis of Stable Pyrrole-Fused Diazacyclic Allenes
Cyclic allenes are a unique class of organic compounds, interest in which has increased dramatically since the inclusion of heteroatoms such as oxygen, sulfur, and especially nitrogen in the ring. Heterocyclic allenes can be subdivided into highly reactive synthons and stable compounds with useful properties. By varying only the reaction time we can control the regioselectivity of the process and synthesize two types of pyrrole-fused diazecines including a rare class of compounds─diazacyclic allenes.
Authors
- Alexander А. Titov (ORCID: https://orcid.org/0000-0001-8943-0362)
- А. В. Варламов (ORCID: https://orcid.org/0000-0003-2320-8747)
- Pavel V. Raspertov
- Rafael Luque (ORCID: https://orcid.org/0000-0003-4190-1916)
- Leonid G. Voskressensky (ORCID: https://orcid.org/0000-0002-9676-5846)
- С. А. Ковалева
- A. P. Novikov
Institutions
- Peoples' Friendship University of Russia (RU)
- Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (RU)
- Federal Research Centre «Fundamentals of Biotechnology» of the Russian Academy of Sciences (RU)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2026-05-22
- DOI
- https://doi.org/10.1021/acs.joc.6c00747
- Primary Topic
- Synthesis and Characterization of Pyrroles
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Russian Science Foundation