What Makes the Lower Urban Land Coverage City a Deeper Ozone Trap: Implications from a Case Study in the Sichuan Basin, Southwest China

The urban–rural gradient of surface ozone concentration is closely associated with urban scale and has been widely reported in megacities globally. However, in the Sichuan Basin of southwestern China, a paradoxical asymmetric pattern between the ozone gradient and the physical urban footprint has emerged. By integrating multi-source satellite observations (e.g., TROPOMI), reanalysis data (ERA5-Land), and a concentric-ring spatial gradient analysis, we quantify a dipole-like urban surface ozone trap pattern in two megacities (Chengdu and Chongqing) from 2013 to 2019. We found that the urban–rural ozone gradients in Chongqing were substantially steeper than those in Chengdu, despite Chongqing’s smaller physical urban footprint. Specifically, in winter, the maximum daily average 8 h ozone level in the urban core drops to 27.5 μg m−3 in Chongqing and 47.9 μg m−3 in Chengdu, with outward radial increasing rates of 6.49% and 1.88% per 10 km, respectively. Conversely, the absolute nitrogen dioxide level in Chengdu is higher, highlighting an asymmetric titration behavior between the two cities. Regarding the chemical regime, analysis of the ratio (β) of nitrogen dioxide to formaldehyde reveals that Chongqing’s core operates under a more severe VOC-limited environment (β is 2.53 and radial gradient is −6.77% per 10 km) compared to Chengdu (β is 2.43 and gradient is −5.34% per 10 km). Furthermore, vertical cross-section analyses indicate that Chongqing’s deep-valley topography induces severe boundary layer compression and aerodynamic stagnation. Thus, rather than acting independently, these localized meteorological constraints function as crucial physical modulators that trap precursor emissions and exacerbate the non-linear chemical titration. This study elucidates how synergistic interactions between basin topography, physical urban footprints, and atmospheric chemistry shape localized ozone traps, providing a referable perspective for assessing complex urban atmospheric environments.