Influence of Carbonated Recycled Concrete Powder on Hydration, Shrinkage and Mechanical Performance of OPC-FA Systems

The effective utilization of recycled concrete powder remains a key challenge for sustainable construction. In this study, carbonated recycled concrete powder (CRCP) was applied to replace cement at levels of 4–16% in Portland cement–fly ash (OPC-FA) systems, and its effects on fresh properties, hydration behavior, shrinkage, pore structure, and mechanical performance were systematically investigated. The incorporation of CRCP reduced flowability and accelerated setting, while slightly advancing and enhancing the main hydration peak at 4–8% replacement, accompanied by higher CH at early ages and increased C–S–H formation at later stages. More significantly, the addition of CRCP substantially decreased both autogenous and drying shrinkage, achieving reductions in the ranges of 6.0–21.4% and 3.2–24.1%, respectively. This improvement is primarily attributed to the elevated internal relative humidity and the lowered capillary pressure within the system. In addition, the mechanical properties exhibited a clear optimum with the addition of 8% CRCP, where the 28 d compressive strength and flexural strengths increased by 16.3% and 4.0%, respectively. Further analysis indicates that this improvement is associated with a higher fraction of high-modulus regions and an increase in average elastic modulus from 23.89 GPa to 27.42 GPa, reflecting a denser microstructure. These results demonstrate that CRCP can effectively regulate hydration and microstructure, providing a feasible approach for improving dimensional stability and mechanical performance while enabling the value-added utilization of recycled concrete powder.