Molecular Formation as Emergent Interference Clustering in the ASFM Model

This preprint presents a molecular-formation extension based on the Asymmetric Source Field Model (ASFM). ASFM itself is introduced and formulated in the related atomic-valence manuscript cited below. The present work applies this residual-field formalism to molecular formation and investigates whether selected bonding, non-bonding, and compression-limited systems can be interpreted as persistent multi-center residual-field coherence clusters. The manuscript discusses O₂, H₂O, Ne-F, CO₂, and exploratory C/N/O/S comparison cases. Molecular formation is treated as the emergence of bridge-coherence clusters between atomic source-field signatures. The pair scans do not include a target-distance term for known molecular bond lengths. Closed-shell systems such as He and Ne are treated as non-bond-active controls. The work further includes an outlook on sequential H₂O angular formation, where a water-like high-response interval emerges without using the empirical H-O-H angle as a target term. The present record is intended as a methodological preprint and reproducibility package. It does not claim a completed frozen-protocol benchmark or a replacement of established quantum chemistry. Rather, it documents the current ASFM-based field-topological approach to molecular structure formation and provides manuscripts, source files, figures, code, and metadata for transparent review.

Authors

Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2026-05-18
DOI
https://doi.org/10.5281/zenodo.20268910
Primary Topic
Advanced Chemical Physics Studies
Type
preprint
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preprint

Molecular Formation as Emergent Interference Clustering in the ASFM Model

Andreas Pernt
Zenodo (CERN European Organization for Nuclear Research)
Advanced Chemical Physics Studies
preprint

Molecular Formation as Emergent Interference Clustering in the ASFM Model

Andreas Pernt
preprint en

Abstract

This preprint presents a molecular-formation extension based on the Asymmetric Source Field Model (ASFM). ASFM itself is introduced and formulated in the related atomic-valence manuscript cited below. The present work applies this residual-field formalism to molecular formation and investigates whether selected bonding, non-bonding, and compression-limited systems can be interpreted as persistent multi-center residual-field coherence clusters. The manuscript discusses O₂, H₂O, Ne-F, CO₂, and exploratory C/N/O/S comparison cases. Molecular formation is treated as the emergence of bridge-coherence clusters between atomic source-field signatures. The pair scans do not include a target-distance term for known molecular bond lengths. Closed-shell systems such as He and Ne are treated as non-bond-active controls. The work further includes an outlook on sequential H₂O angular formation, where a water-like high-response interval emerges without using the empirical H-O-H angle as a target term. The present record is intended as a methodological preprint and reproducibility package. It does not claim a completed frozen-protocol benchmark or a replacement of established quantum chemistry. Rather, it documents the current ASFM-based field-topological approach to molecular structure formation and provides manuscripts, source files, figures, code, and metadata for transparent review.

Zenodo (CERN European Organization for Nuclear Research)
Advanced Chemical Physics Studies
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