Triethanolamine Borate with a Rigid, Nonplanar Configuration as an Unexpectedly Highly Efficient Coreactant for Tris(2,2′-bipyridine)ruthenium(II) Electrochemiluminescence

-labeled microbeads by employing ECL microscopy. Under chronoamperometric conditions, TEAB unprecedentedly exhibits 74- and 60-fold higher ECL than TPrA at 0.925 V as well as 11- and 25-fold higher ECL than TPrA at 1.3 V on Au and Pt electrodes, respectively. These results highlight TEAB as a user-friendly and highly promising alternative to TPrA, with significant potential to advance analytical and diagnostic applications.

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Publication Details

Journal
Analytical Chemistry
Published
2026-05-18
DOI
https://doi.org/10.1021/acs.analchem.6c01089
Primary Topic
Advanced biosensing and bioanalysis techniques
Type
article
Field-Weighted Citation Impact
0.00

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article

Triethanolamine Borate with a Rigid, Nonplanar Configuration as an Unexpectedly Highly Efficient Coreactant for Tris(2,2′-bipyridine)ruthenium(II) Electrochemiluminescence

Fathimath Abbas, Solomon Sime Tessema, Tsegu Lijalem, Francesca Romana Lauro et al.
Analytical Chemistry
Advanced biosensing and bioanalysis techniques
article

Triethanolamine Borate with a Rigid, Nonplanar Configuration as an Unexpectedly Highly Efficient Coreactant for Tris(2,2′-bipyridine)ruthenium(II) Electrochemiluminescence

Fathimath Abbas, Solomon Sime Tessema, Tsegu Lijalem, Francesca Romana Lauro, Dejana Bešlić, Neso Sojic, Guobao Xu, Wenxin Niu, Zhiyong Dong
article en

Abstract

-labeled microbeads by employing ECL microscopy. Under chronoamperometric conditions, TEAB unprecedentedly exhibits 74- and 60-fold higher ECL than TPrA at 0.925 V as well as 11- and 25-fold higher ECL than TPrA at 1.3 V on Au and Pt electrodes, respectively. These results highlight TEAB as a user-friendly and highly promising alternative to TPrA, with significant potential to advance analytical and diagnostic applications.

Analytical Chemistry
University of Science and Technology of China (CN), Centre National de la Recherche Scientifique (FR), Université de Bordeaux (FR), Chinese Academy of Sciences (CN), Institut des Sciences Moléculaires (FR), Changchun Institute of Applied Chemistry (CN), Institut Polytechnique de Bordeaux (FR)
Agence Nationale de la Recherche, National Natural Science Foundation of China, Chinese Academy of Sciences, Ministry of Science and Technology of the People's Republic of China, China Scholarship Council, Centre National de la Recherche Scientifique, Alliance of International Science Organizations
Openalex Percentile: Top 8%
Advanced biosensing and bioanalysis techniques
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