Mg-Catalyzed Nucleophilic Cage B–H Amination of <i>o</i> -Carborane

-carboranes. A reaction mechanism was proposed with in situ-generated amino magnesium species as the reactive nucleophile and catalyst. This transformation offered a cost-effective, environmentally benign, and sustainable strategy for carborane cage BH amination.

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Publication Details

Journal
Organic Letters
Published
2026-05-12
DOI
https://doi.org/10.1021/acs.orglett.6c01551
Primary Topic
Boron Compounds in Chemistry
Type
article
Field-Weighted Citation Impact
0.00
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article

Mg-Catalyzed Nucleophilic Cage B–H Amination of o -Carborane

Chen Huang, J N Zhang, Q. Zhuo, Zuowei Xie
Organic Letters
Boron Compounds in Chemistry
article

Mg-Catalyzed Nucleophilic Cage B–H Amination of o -Carborane

Chen Huang, J N Zhang, Q. Zhuo, Zuowei Xie
article en

Abstract

-carboranes. A reaction mechanism was proposed with in situ-generated amino magnesium species as the reactive nucleophile and catalyst. This transformation offered a cost-effective, environmentally benign, and sustainable strategy for carborane cage BH amination.

Organic Letters
Chinese University of Hong Kong (HK), Southern University of Science and Technology (CN)
Openalex Percentile: Top 5%
Boron Compounds in Chemistry
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