Isolable Phosphonioacetylides as Strong Neutral Carbon Donors with Variable Steric Demand and Tunable Donor Properties
moiety thermally or upon hydrolysis. These results establish design principles for stabilizing and tuning phosphonioacetylides and open avenues for their use in coordination chemistry and catalysis.
Authors
- Klaus Wurst (ORCID: https://orcid.org/0000-0002-8774-9051)
- Christopher B. Caputo (ORCID: https://orcid.org/0000-0002-7523-0324)
- Fabian Dielmann (ORCID: https://orcid.org/0000-0002-7025-5450)
- Lucas C. Torres
- Franka Brylak (ORCID: https://orcid.org/0000-0003-1590-9324)
- Michael Seidl
- Liane Perktold
- Luis Stechele
Institutions
- Universität Innsbruck (AT)
- York University (CA)
- Institute of General and Inorganic Chemistry (BG)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-05-12
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c00919
- Primary Topic
- Phosphorus compounds and reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Mitacs
- Universität Innsbruck
- Natural Sciences and Engineering Research Council of Canada