Ni(II) Complexes Based on a Pyridyl Phosphonium Ylide Ligand
Ni(II) complexes bearing a chelating pyridyl non-stabilized phosphonium ylide ligand were synthesized and fully characterized. Dependent on the denticity of the pre-ligand used, either a homoleptic Ni complex adopting a cis-ylide configuration or a Ni pincer-type complex was obtained. The latter constitutes an unprecedented stable P-ylide Ni(II) complex featuring a Ni–Cl bond and characterized by X-ray diffraction analysis.
Authors
- Olivier Baslé (ORCID: https://orcid.org/0000-0002-4551-473X)
- Jean‐Baptiste Sortais (ORCID: https://orcid.org/0000-0003-1178-8588)
- Carine Duhayon (ORCID: https://orcid.org/0000-0001-7345-8782)
- Oussama Fayafrou (ORCID: https://orcid.org/0009-0000-0047-0174)
- Mohamed Yahia (ORCID: https://orcid.org/0000-0002-0063-9408)
- Yves Canac (ORCID: https://orcid.org/0000-0002-3747-554X)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université Fédérale de Toulouse Midi-Pyrénées (FR)
- Laboratoire de Chimie de Coordination (FR)
Publication Details
- Journal
- Organometallics
- Published
- 2026-05-12
- DOI
- https://doi.org/10.1021/acs.organomet.6c00046
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Agence Nationale de la Recherche
- Centre National de la Recherche Scientifique