Halo- and Cyano-Sulfonylation of BCB-Tethered Allyl Amides via Photoredox-Catalyzed Radical-Polar Crossover
-trig cyclization/radical-polar crossover cascade that proceeds across the strained C-C bond of the BCBs and a C═C bond. Notable features of this approach include the formation of three new chemical bonds in a single step, complete atom economy, and the versatile derivatization of the products.
Authors
- Jiao Zhou (ORCID: https://orcid.org/0000-0002-4015-427X)
- Yu Liu (ORCID: https://orcid.org/0000-0003-4555-8238)
- Chang-Deng Liu
- Rui Zeng
- Jian-Hong Fan (ORCID: https://orcid.org/0009-0009-0136-8281)
- Peng-Fei Xia
Institutions
- Hunan Institute of Science and Technology (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2026-05-12
- DOI
- https://doi.org/10.1021/acs.joc.6c00608
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Hunan Province