Isomerism and Relaxation Properties of Lanthanide(III) Complexes of a Ditopic Ligand with Two DO3A Units Bridged by a Methylene-bis(phosphinate) Spacer

, 0.94 T, 25 °C) is among the highest values measured for a monohydrated dinuclear complex and is almost the same at 0.94 and 7 T. Since the methylene group of the bridge can be synthetically modified, this paves the way to targeted magnetic resonance imaging (MRI) contrast agents (CAs) with high relaxivity at high magnetic fields.

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Journal
Inorganic Chemistry
Published
2026-05-12
DOI
https://doi.org/10.1021/acs.inorgchem.6c00452
Primary Topic
Lanthanide and Transition Metal Complexes
Type
article
Field-Weighted Citation Impact
0.00

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article

Isomerism and Relaxation Properties of Lanthanide(III) Complexes of a Ditopic Ligand with Two DO3A Units Bridged by a Methylene-bis(phosphinate) Spacer

Petr Hermann, Adam Svítok, Carlos Platas-Iglesias
Inorganic Chemistry
Lanthanide and Transition Metal Complexes
article

Isomerism and Relaxation Properties of Lanthanide(III) Complexes of a Ditopic Ligand with Two DO3A Units Bridged by a Methylene-bis(phosphinate) Spacer

Petr Hermann, Adam Svítok, Carlos Platas-Iglesias
article en

Abstract

, 0.94 T, 25 °C) is among the highest values measured for a monohydrated dinuclear complex and is almost the same at 0.94 and 7 T. Since the methylene group of the bridge can be synthetically modified, this paves the way to targeted magnetic resonance imaging (MRI) contrast agents (CAs) with high relaxivity at high magnetic fields.

Inorganic Chemistry
Universidade da Coruña (ES), Charles University (CZ), Rede de Química e Tecnologia (PT)
Grantová Agentura, Univerzita Karlova, Ministerio de Ciencia, Innovación y Universidades, Grantová Agentura České Republiky, Xunta de Galicia
Openalex Percentile: Top 11%
Lanthanide and Transition Metal Complexes
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Isomerism and Relaxation Properties of Lanthanide(III) Complexes of a Ditopic Ligand with Two DO3A Units Bridged by a Methylene-bis(phosphinate) Spacer — Petr Hermann, Adam Svítok, et al. · Inorganic Chemistry (2026) | TGRS Research Map | TGRS