Cavity quantum electrodynamics ring coupled cluster and the random phase approximation
It is well known that the ground-state correlation energy from the particle-hole channel of the random phase approximation (RPA) is formally equivalent to that from a simplified coupled cluster doubles (CCD) model that includes only ring-diagram contraction contributions in the residual equations [Scuseria et al., J. Chem. Phys. 129, 231101 (2008)]. We generalize this analytic result to the cavity quantum electrodynamics (QED) case and demonstrate the numerical equivalence of QED-RPA and a QED ring-CCD model that accounts for double electron excitations, coupled single-electron excitations/single-photon creation, and double-photon creation.
Authors
- Stephen H. Yuwono (ORCID: https://orcid.org/0000-0002-6604-3543)
- Henk Eshuis (ORCID: https://orcid.org/0000-0002-2415-2856)
- A. Eugene DePrince
Institutions
- Florida State University (US)
- Montclair State University (US)
Publication Details
- Journal
- The Journal of Chemical Physics
- Published
- 2026-05-12
- DOI
- https://doi.org/10.1063/5.0327154
- Primary Topic
- Strong Light-Matter Interactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00