Cavity quantum electrodynamics ring coupled cluster and the random phase approximation

It is well known that the ground-state correlation energy from the particle-hole channel of the random phase approximation (RPA) is formally equivalent to that from a simplified coupled cluster doubles (CCD) model that includes only ring-diagram contraction contributions in the residual equations [Scuseria et al., J. Chem. Phys. 129, 231101 (2008)]. We generalize this analytic result to the cavity quantum electrodynamics (QED) case and demonstrate the numerical equivalence of QED-RPA and a QED ring-CCD model that accounts for double electron excitations, coupled single-electron excitations/single-photon creation, and double-photon creation.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2026-05-12
DOI
https://doi.org/10.1063/5.0327154
Primary Topic
Strong Light-Matter Interactions
Type
article
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article

Cavity quantum electrodynamics ring coupled cluster and the random phase approximation

Stephen H. Yuwono, Henk Eshuis, A. Eugene DePrince
The Journal of Chemical Physics
Strong Light-Matter Interactions
article

Cavity quantum electrodynamics ring coupled cluster and the random phase approximation

Stephen H. Yuwono, Henk Eshuis, A. Eugene DePrince
article en

Abstract

It is well known that the ground-state correlation energy from the particle-hole channel of the random phase approximation (RPA) is formally equivalent to that from a simplified coupled cluster doubles (CCD) model that includes only ring-diagram contraction contributions in the residual equations [Scuseria et al., J. Chem. Phys. 129, 231101 (2008)]. We generalize this analytic result to the cavity quantum electrodynamics (QED) case and demonstrate the numerical equivalence of QED-RPA and a QED ring-CCD model that accounts for double electron excitations, coupled single-electron excitations/single-photon creation, and double-photon creation.

The Journal of Chemical PhysicsVol. 164(18)
Florida State University (US), Montclair State University (US)
Affordable and clean energy
Openalex Percentile: Top 6%
Strong Light-Matter Interactions
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Cavity quantum electrodynamics ring coupled cluster and the random phase approximation — Stephen H. Yuwono, Henk Eshuis, et al. · The Journal of Chemical Physics (2026) | TGRS Research Map | TGRS