Carboxyphenolate Coordination Frameworks for High‐Voltage Calcium Storage

with a Coulombic efficiency of 99.8%, retaining 75% of its initial capacity after 200 cycles at a C/20 rate. This study demonstrates, the use of reduced-state conjugated carboxyphenolate frameworks as active materials for high voltage divalent cation storage, highlighting how spectator cations and framework flexibility influence redox potential and long-term stability in Ca-ion batteries.

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Publication Details

Journal
Advanced Science
Published
2026-05-11
DOI
https://doi.org/10.1002/advs.75481
Primary Topic
Advancements in Battery Materials
Type
article
Field-Weighted Citation Impact
0.00

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article

Carboxyphenolate Coordination Frameworks for High‐Voltage Calcium Storage

Darsi Rambabu, Petru Apostol, Shubhadeep Pal, Tom Goossens et al.
Advanced Science
Advancements in Battery Materials
article

Carboxyphenolate Coordination Frameworks for High‐Voltage Calcium Storage

Darsi Rambabu, Petru Apostol, Shubhadeep Pal, Tom Goossens, Taniya Purkait, Vasudeva Rao Bakuru, Xiaolong Guo, Augustin Ramackers, Viliam Frano, Xiaodong Lin, Da Tie, Robert Markowski, Alexandru Vlad
article en

Abstract

with a Coulombic efficiency of 99.8%, retaining 75% of its initial capacity after 200 cycles at a C/20 rate. This study demonstrates, the use of reduced-state conjugated carboxyphenolate frameworks as active materials for high voltage divalent cation storage, highlighting how spectator cations and framework flexibility influence redox potential and long-term stability in Ca-ion batteries.

Advanced Science
SRM University (IN), Walloon Excellence in Lifesciences and Biotechnology (BE), UCLouvain (BE)
Fonds Wetenschappelijk Onderzoek, European Research Council
Affordable and clean energy
Openalex Percentile: Top 9%
Advancements in Battery Materials
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Carboxyphenolate Coordination Frameworks for High‐Voltage Calcium Storage — Darsi Rambabu, Petru Apostol, et al. · Advanced Science (2026) | TGRS Research Map | TGRS