Plateau moduli of Kremer–Grest models for commodity polymer melts

We estimate the plateau moduli of end-pinned bead-spring polymer melts with Z = 100 and Z = 200 entanglements per chain from the time-dependent elastic response to a step strain, which we first extrapolate to infinite time and then interpolate to zero strain. We present data for systems deformed in the melt state and for systems deformed at the primitive path level following the recent inverse primitive path analysis protocol. We observe excellent agreement between the plateau moduli obtained via the two deformation protocols and good agreement with the available experimental data for commodity polymer melts using a common mapping on the Kuhn scale.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2026-05-11
DOI
https://doi.org/10.1063/5.0325589
Primary Topic
Rheology and Fluid Dynamics Studies
Type
article
Field-Weighted Citation Impact
0.00

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article

Plateau moduli of Kremer–Grest models for commodity polymer melts

Carsten Svaneborg, Ralf Everaers
The Journal of Chemical Physics
Rheology and Fluid Dynamics Studies
article

Plateau moduli of Kremer–Grest models for commodity polymer melts

Carsten Svaneborg, Ralf Everaers
article en

Abstract

We estimate the plateau moduli of end-pinned bead-spring polymer melts with Z = 100 and Z = 200 entanglements per chain from the time-dependent elastic response to a step strain, which we first extrapolate to infinite time and then interpolate to zero strain. We present data for systems deformed in the melt state and for systems deformed at the primitive path level following the recent inverse primitive path analysis protocol. We observe excellent agreement between the plateau moduli obtained via the two deformation protocols and good agreement with the available experimental data for commodity polymer melts using a common mapping on the Kuhn scale.

The Journal of Chemical PhysicsVol. 164(18)
École Normale Supérieure de Lyon (FR), Centre National de la Recherche Scientifique (FR), University of Southern Denmark (DK), Laboratoire de Physique de l'ENS de Lyon (FR)
Partnership for Advanced Computing in Europe AISBL, Danish e-Infrastructure Cooperation
Openalex Percentile: Top 10%
Rheology and Fluid Dynamics Studies
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Plateau moduli of Kremer–Grest models for commodity polymer melts — Carsten Svaneborg, Ralf Everaers · The Journal of Chemical Physics (2026) | TGRS Research Map | TGRS