Short Glass Fiber-Reinforced Recycled Polyethylene Terephthalate Composites for Additive Manufacturing: Modification Strategies, Processing, Characterization and 3D Printing

In response to the growing demand for sustainable manufacturing, 3D printing using recycled polyethylene terephthalate (rPET) offers a novel waste-to-value conversion method. Although the application of rPET in additive manufacturing has attracted significant attention from both the academic and industrial sectors, substantial challenges impede its further development, notably the high processing shrinkage and poor mechanical properties of the final product. This study focuses on developing recycled PET-based composites with favorable processing, thermal, and mechanical properties. Regranulates were produced via twin-screw extrusion using PET flakes, multifunctional chain extenders, and short glass fibers (GFs). The rPET-GF composites were characterized in terms of their processing, thermal, thermomechanical, and mechanical properties. Epoxy-functional chain extender modification effectively increased the molecular weight and improved the processability, whereas GF reinforcement enhanced the tensile properties of both injection-molded and FDM-manufactured parts. A primary advantage of the rPET systems developed in this study is their delayed crystallization kinetics. These findings highlight the significant potential of the composites developed herein for extrusion-based additive manufacturing (MEX-AM), as delayed crystallization facilitates enhanced interfacial adhesion, lower volumetric shrinkage, and superior dimensional stability.