Microporous Self‐Assembled Pd(II) Tetrahedral Cages for Rapid and Reversible Multi‐Phase Sequestration of Iodine and Methyl Iodide
). DFT calculations indicate that the observed performance originates from cooperative π-iodine interactions and nucleophilic heteroatom binding. Combined with structural robustness, recyclability, and scalable synthesis, these coordination cages establish a new benchmark and represent the first example of dynamic vapor-phase iodine capture by coordination cages.
Authors
- Debashree Manna (ORCID: https://orcid.org/0000-0002-1080-8068)
- Dipak Samanta (ORCID: https://orcid.org/0000-0002-3474-3588)
- Raghunath Singha (ORCID: https://orcid.org/0009-0002-9273-6746)
- Monotosh Dalapati (ORCID: https://orcid.org/0009-0008-6205-0683)
- Pijush De
- Risikeshan Pradhan
Institutions
- National Institute of Science Education and Research (IN)
- Institute of Organic Chemistry (PL)
- Czech Academy of Sciences, Institute of Organic Chemistry and Biochemistry (CZ)
Publication Details
- Journal
- Small
- Published
- 2026-05-10
- DOI
- https://doi.org/10.1002/smll.73642
- Primary Topic
- Covalent Organic Framework Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Department of Atomic Energy, Government of India