Countable Basis for Free Electromagnetic Fields

ABSTRACT Polychromatic electromagnetic fields are expanded as integrals over monochromatic fields, such as plane waves, multipolar fields, or Bessel beams. However, monochromatic fields do not belong to the Hilbert space of free Maxwell fields, since their norms diverge. Moreover, the continuous frequency integrals involved in such expansions complicate the treatment of light–matter interactions via the scattering operator. Here, we identify and study a polychromatic basis for free Maxwell fields whose basis vectors belong to the Hilbert space. These vectors are defined as simultaneous eigenstates of four commuting operators with integer eigenvalues. As a consequence, the basis set is countable, and the electromagnetic Hilbert space is separable and isomorphic to , the Hilbert space of square‐summable sequences. Each basis vector represents a polychromatic single‐photon wave with quantized energy and a wavelet‐like temporal dependence. Three versions of this basis are defined: Regular, incoming, and outgoing. The fields of the regular basis are smooth in both space and time. The incoming and outgoing fields are likewise smooth, except at the spatial origin. These results support and motivate the use of countable bases for both the theoretical description and the practical computation of light–matter interactions.