Alkenyl Fluorosulfates—Expedient Partners for Palladium‐Catalyzed Cross‐Coupling Reactions

were documented. Reactivity of alkenyl fluorosulfates in Suzuki, Sonogashira, Heck, Stille, and Buchwald-Hartwig reactions, as well as Miyaura borylation under typical conditions, was studied, and limitations of the methods were established. It was found that alkenyl flurosulfates have similar or even higher reactivity in the cross-coupling reactions as compared to alkenyl triflates.

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Publication Details

Journal
Chemistry - A European Journal
Published
2026-05-09
DOI
https://doi.org/10.1002/chem.71098
Primary Topic
Catalytic Cross-Coupling Reactions
Type
article
Field-Weighted Citation Impact
0.00

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article

Alkenyl Fluorosulfates—Expedient Partners for Palladium‐Catalyzed Cross‐Coupling Reactions

Serhii Zhersh, Vladyslav Hnativ, Oleksandr O. Grygorenko, Serhii Aleksandrenko
Chemistry - A European Journal
Catalytic Cross-Coupling Reactions
article

Alkenyl Fluorosulfates—Expedient Partners for Palladium‐Catalyzed Cross‐Coupling Reactions

Serhii Zhersh, Vladyslav Hnativ, Oleksandr O. Grygorenko, Serhii Aleksandrenko
article en

Abstract

were documented. Reactivity of alkenyl fluorosulfates in Suzuki, Sonogashira, Heck, Stille, and Buchwald-Hartwig reactions, as well as Miyaura borylation under typical conditions, was studied, and limitations of the methods were established. It was found that alkenyl flurosulfates have similar or even higher reactivity in the cross-coupling reactions as compared to alkenyl triflates.

Chemistry - A European Journal
Taras Shevchenko National University of Kyiv (UA), Enamine (Ukraine) (UA)
Ministry of Education and Science of Ukraine
Openalex Percentile: Top 9%
Catalytic Cross-Coupling Reactions
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