High-Frequency Infrared Thermography Reveals Short-Term Pressure Variations in CO2 Natural Vents at Mefite d’Ansanto (Italy)

A thermal infrared (TIR) camera was installed at Mefite Lake in Valle d’Ansanto, Irpinia (Italy), to assess whether small variations in cold CO2 flux can be resolved thermally. To our knowledge, this is the first systematic attempt to extract short-period degassing dynamics from TIR data at Mefite. Infrared thermal images taken over a three-hour nighttime interval revealed the spatial distribution and extent of natural CO2 emissions. The high sampling frequency of one minute detected unexpected thermal variability from the source. The extent of temperature variations across the entire site reached almost 3 °C, with durations typically ranging from a few minutes to tens of minutes. Spectral analysis of the temperature time series reported a 1/f-type noise pattern, with significant periods of 2–3 min, 5 min, 26 min, and 61 min observed at different locations. Further intermediate periods were observed at individual points. Differences and delays in temperature variations appeared to be related to distance from the structure’s centre and the presence of water. These temperature fluctuations were interpreted as changes in the gaseous emission flow caused by a few kPa of CO2 escaping due to pressure variations. The gas thermally interacts with the underlying soil, adding or removing heat at the surface. These results demonstrate that high-frequency infrared thermography provides a sensitive and practical tool for quantifying short-term flux variability at natural CO2 vents and for improving the characterisation of their degassing dynamics.