Precise Control of Water Adsorption Behavior in Solid Solutions of Amorphous Coordination Polymers
- and K-edge X-ray absorption fine structure (XAFS) techniques. Slight differences in the bond energies of bonds in the vicinity of the water-induced amorphous-to-crystalline transformation. This transformation involves a change in the coordination geometry, from tetrahedral to octahedral, through the rearrangement of CN-Co(M) bonds via cleavage/reformation, giving rise to the desirable water uptake characteristics.
Authors
- Benjamin Le Ouay (ORCID: https://orcid.org/0000-0001-7053-4786)
- Yuki Imamura
- Haruka Yoshino (ORCID: https://orcid.org/0000-0003-3102-6222)
- Kohei Yamagami (ORCID: https://orcid.org/0000-0001-6997-6157)
- Hitoshi Miyasaka (ORCID: https://orcid.org/0000-0001-9897-0782)
- Sayuri Shimoda
- Ryo Ohtani (ORCID: https://orcid.org/0000-0003-4840-3338)
- Masaaki Ohba (ORCID: https://orcid.org/0000-0001-9268-3512)
- Hirona Yamagishi
Institutions
- Kyushu University (JP)
- Ritsumeikan University (JP)
- Tohoku University (JP)
- Japan Synchrotron Radiation Research Institute (JP)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2026-05-08
- DOI
- https://doi.org/10.1002/chem.71070
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Japan Society for the Promotion of Science London
- Research Foundation for the Electrotechnology of Chubu