Monolithic Perovskite–Perovskite–Perovskite–Silicon Quadruple-Junction Tandem Solar Cell with Efficiency over 21%

Here, we demonstrate a proof-of-concept perovskite–perovskite–perovskite–silicon quadruple-junction tandem solar cell achieving a power conversion efficiency of 21.4% (steady state at 21.1%) and an open-circuit voltage of 4.01 V. To our knowledge, this is the first perovskite-based quadruple-junction tandem integrated on a silicon bottom cell, demonstrating the feasibility of a silicon-integrated four-junction architecture and establishing a baseline for future device optimization.

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Publication Details

Journal
ACS Energy Letters
Published
2026-05-08
DOI
https://doi.org/10.1021/acsenergylett.6c00879
Primary Topic
Perovskite Materials and Applications
Type
article
Field-Weighted Citation Impact
0.00

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article

Monolithic Perovskite–Perovskite–Perovskite–Silicon Quadruple-Junction Tandem Solar Cell with Efficiency over 21%

Long Lin, Leiping Duan, Jianghui Zheng, Baihong Zhu et al.
ACS Energy Letters
Perovskite Materials and Applications
article

Monolithic Perovskite–Perovskite–Perovskite–Silicon Quadruple-Junction Tandem Solar Cell with Efficiency over 21%

Long Lin, Leiping Duan, Jianghui Zheng, Baihong Zhu, Lijie Zheng, Qingyun Chen, Ying Liu, Bolun Li, Xinqin Liao, Zhong Chen, Jiahui Qi, Yue Sun
article en

Abstract

Here, we demonstrate a proof-of-concept perovskite–perovskite–perovskite–silicon quadruple-junction tandem solar cell achieving a power conversion efficiency of 21.4% (steady state at 21.1%) and an open-circuit voltage of 4.01 V. To our knowledge, this is the first perovskite-based quadruple-junction tandem integrated on a silicon bottom cell, demonstrating the feasibility of a silicon-integrated four-junction architecture and establishing a baseline for future device optimization.

ACS Energy Letters
Xiamen University (CN), Shenzhen Academy of Aerospace Technology (CN)
National Natural Science Foundation of China, Xiamen University, Basic and Applied Basic Research Foundation of Guangdong Province
Affordable and clean energy
Openalex Percentile: Top 9%
Perovskite Materials and Applications
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